You can order a virtual card by signing in to your Revolut Business account. Once you sign in, go to the 'Home' menu, 'Cards' section and create one on the virtual cards page.
There are two types of virtual cards you can order—a personal virtual card or a subscription virtual card, that can only be ordered in the 'Payments' section, Subscripitons tab on paid plans.
See the difference here.
When ordering virtual cards, you will need to specify who the card should belong to— this can be a team member or yourself.